|UN 1436 4.3(4.2)/PG II|
SECTION 1. IDENTIFICATION
Product Name: Zinc-66 metal Isotope
Product Number: every applicable American aspects product codes, e.g. ZN-M-01-ISO.066I
CAS #: 14378-33-7
Relevant established uses that the substance: scientific research and also development
Emergency telephone number:Domestic, north America: +1 800-424-9300International: +1 703-527-3887
SECTION 2. Perils IDENTIFICATION
Classification that the building materials or mixture:The mixture is classified follow to: Regulation EC 1272/2008
Signal Words: Danger.Hazard Statements:H250 catches fire spontaneously if exposed come air.H260 In contact with water publication flammable gases which may ignite spontaneously.H400 an extremely toxic to aquatic life.H410 really toxic come aquatic life with resilient effects.Precautionary Statements:P210 save away from heat, hot surfaces, sparks, open flames and also other ignition sources. No smoking.P222 do not enable contact with air.P231 + P232 Handle and store contents under inert gas. Protect from moisture.P223 carry out not permit contact v water.P233 save container strict closed.P273 prevent release come the environment.P280 Wear protective gloves/protective clothing.P302 + P334 IF top top SKIN: Immerse in cool water or plunder in wet bandages.P391 collection spillage.Other hazards: none known.
SECTION 3. COMPOSITION/INFORMATION ~ above INGREDIENTS
Substance name (IUPAC/EC):Zinc steel Isotope
SECTION 4. An initial AID MEASURES
Description of first aid measures:In case of inhalation: If breathed in, move human into new air. If no breathing, give fabricated respiration. Consult a physician.In case of skin contact: wash off through soap and plenty that water. Above a physician.In instance of eye contact: flush eyes v water as a precaution.In situation of ingestion: Never offer anything by mouth to an unconscious person. Rinse mouth with water. Top a physician.
Most crucial symptoms and also effects, both acute and also delayed:Inhalation: might be harmful if inhaled; may reason respiratory street irritation.Eyes: May reason eye irritation.Skin contact: may be harmful if absorbed through skin; may reason skin irritation.
Ingestion: might be harmful if swallowed.Indication of any type of immediate medical attention and also special therapy needed: treat symptomatically. Show this safety and security data sheet to a physician or emergency room.
SECTION 5. FIREFIGHTING MEASURES
Extinguisher media:Suitable extinguisher media: dry sand, clay, approved course D extinguishers.Unsuitable extinguishing media: Water spray.Special hazards occurring from the mixture: Flammable. Well dust distributed in air might ignite. Pyrophoric: Spontaneouslyflammable in air. Water-reactive. Call with water liberates extremely flammable gases. Thermal decompositioncan bring about release that irritating gases and vapours. Save product and also empty container away from heat and also sources the ignition.Advice for fire-fighters: stay self-contained breathing apparatus because that firefighting if necessary.Further information: use water spray come cool unopened containers.
SECTION 6. ACCIDENTAL release MEASURES
Personal precautions, protective equipment and also emergency procedures:Personal precautions: stop dust formation. Ensure sufficient ventilation. Remove all sources of ignition. Evacuatepersonnel to safe areas.Environmental precautions: protect against product native entering drains. Prevent more leakage or spillage if for sure to do so.Local authorities need to be recommend if far-ranging spillages can not be contained.Methods because that containment and also cleaning up:Methods for cleaning up: choose up and arrange handle without creating dust. Do not flush through water. Save insuitable, closed containers for disposal.Reference to other sections:Treat recovered material as described in the section "Disposal considerations".
SECTION 7. HANDLING and also STORAGE
Precautions for for sure handling:Advice on for sure handling: carry out appropriate exhaust ventilation at places where dust is formed. Further processingof solid products may an outcome in the development of combustible dusts. Store away from sources of ignition. Provide appropriate exhaust at places where dust is formed.Hygiene measures: execute not eat, drink or smoke once using this product.Conditions for for sure storage, including incompatibilities:Requirements for storage areas and also containers: store in cool place. Keep container tightly closed in a dry and also wellventilated place.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational exposure limits: contains no building materials with work-related exposure border values.Exposure controls:Appropriate engineering controls: Use just under a chemical fume hood. Ensure that eyewash stations and also safety showers space close come the workstation location.Individual defense measures, together as an individual protective equipment:Eye/face protection: confront shield and safety glasses: Use tools for eye defense tested and approved under appropriate government standards such together NIOSH (US) or EN 166(EU).Hand protection: The selected safety gloves must accomplish the specifications of EU Directive 89/686/EEC and thestandard EN 374 derived from it. Handle product with gloves.Body protection: choose body protection according to the amount and also concentration of the dangerous problem at the workplace.Respiratory protection: Where danger assessment shows air-purifying respirators are appropriate use a full-face particlerespirator form N100 (US) or type P3 (EN 143) respirator cartridges as a back-up to engineering controls. If the respirator is the sole means of protection, use a full-face provided air respirator. Usage respirators and components tested and approved under proper government criter such together NIOSH (US) or CEN (EU).
SECTION 9. PHYSICAL and CHEMICAL PROPERTIES
Appearance (form): hard (powder).Colour: Grey.Odour: Odourless.Odour threshold: No data available.Molecular Weight: 65.39pH (concentration): No data available.Melting point/range (°C): 419 °CBoiling point/range (°C): 907 °CFreezing suggest (°C): No data available.Flash point (°C): No data available.Evaporation rate: No data available.Flammability (solid, gas): The problem is a flammable solid.Ignition temperature (°C): No data available.Upper/lower flammability/explosive limits: No data available.Vapour pressure (20 °C): No data availableVapour density: 7133 g/mL in ~ 25 °CRelative density (25 °C): No data available.Water solubility (g/L) in ~ 20 °C: Insoluble.n-Octanol/Water partition coefficient: No data available.Auto-ignition temperature: No data available.Decomposition temperature: No data available.Viscosity, dynamic (mPa s): No data available.Explosive properties: throughout processing, dust may form explosive mixture in air.Oxidising properties: The substance or mixture is not classified together oxidizing.
SECTION 10. STABILITY and REACTIVITY
Reactivity: No dangerous reaction well-known under problems of normal use.Chemical stability: Water-reactive, moisture-sensitive, air-sensitive, pyrophoric: spontaneously flammable in air.Possibility the hazardous reactions: reacts violently with water.Conditions come avoid: Heat, flames and sparks, moisture, dust formation.Incompatible materials: strong acids and oxidizing agents.Hazardous decomposition products: Zinc/zinc oxides, zinc oxide fumes.
SECTION 11. TOXICOLOGICAL INFORMATION
Information ~ above toxicological effects:Not classified based on obtainable information.Classification according to GHS (1272/2008/EG, CLP)Skin corrosion/irritation:Not divide based on obtainable information.Serious eye damage/eye irritation:Not classified based on easily accessible information.Respiratory or skin sensitisation:Not classified based on obtainable information.Germ cell mutagenicity:Not classified based on easily accessible information.Carcinogenicity:IARC: No ingredient of this product current at levels higher than or same to 0.1% is figured out as a probable,possible or confirmed human carcinogen by IARC.ACGIH: No ingredient of this product existing at levels better than or equal to 0.1% is figured out as a carcinogen orpotential carcinogen by ACGIH.NTP: No ingredient of this product existing at levels better than or equal to 0.1% is determined as a recognized oranticipated carcinogen through NTP.OSHA: No component of this product present at levels greater than or same to 0.1% is established as a carcinogen orpotential carcinogen through OSHA.Reproductive toxicity:Not share based on easily accessible information.Specific target organ toxicity – single exposure (STOT):Not classified based on accessible information.Specific target body organ toxicity (STOT) – repeated exposure:Not classified based on easily accessible information.Aspiration toxicity:Not divide based on obtainable information.
SECTION 12. Environmental INFORMATION
Toxicity:Toxicity come Fish: LC50 – Cyprinus carpio (carp) – 450 ug/l – 96 hToxicity come Daphnia and Other Aquatic Invertebrates: LC50 – Daphnia magna (water flea) – 0.068 mg/l – 48 hMortality NOEC – Daphnia (water flea) 0.101 – 0.14 mg/l – 7 dPersistence and degradability: No data available.Bioaccumulative potential: Bioaccumulation: algae – 7 d in ~ 16 °C – 5 ug/l. Bioconcentration element (BCF): 466Mobility in soil: No data available.Results that PBT& vPvB assessment: not relevant.Other disadvantage effects: An ecological hazard cannot be excluded in the occasion of unprofessional handling or disposal. Very toxic to aquatic life, with durable effects.
SECTION 13. Handle CONSIDERATIONS
Waste therapy methods: Burn in a chemistry incinerator equipped with an afterburner and also scrubber yet exert extra care in igniting as this material is extremely flammable. Watch all local and national ecological regulations. Call a licensed skilled waste disposal organization to dispose that this material.
SECTION 14. Transfer INFORMATION
DOT:Proper Shipping Name: ZINC POWDER.Hazard Class: 4.3Subsidiary risk Class: 4.2UN Number: 1436Packing Group: IIHazard Label:TDG:Proper Shipping Name: ZINC POWDER.Hazard Class: 4.3Subsidiary peril Class: 4.2UN Number: 1436Packing Group: IIIATA:Proper Shipping Name: ZINC POWDER.Hazard Class: 4.3Subsidiary risk Class: 4.2UN Number: 1436Packing Group: IIIMDG:Proper Shipping Name: ZINC POWDER.Hazard Class: 4.3Subsidiary danger Class: 4.2UN Number: 1436Packing Group: II
SECTION 15. Regulation INFORMATION
EU regulations:Regulation (EC) No. 1005/2009 on building materials that diminish the ozone layer, Annex I and II, together amendedNot listed.Regulation (EC) No. 850/2004 on persistent organic pollutants, Annex INot listed.Regulation (EU) No. 649/2012 concerning the export and also import of attention chemicals, Annex I, component 1 asamendedNot listed.Regulation (EU) No. 649/2012 worrying the export and import of danger chemicals, Annex I, component 2 asamendedNot listed.Regulation (EU) No. 649/2012 worrying the export and also import of dangerous chemicals, Annex I, part 3 asamendedNot listed.Regulation (EU) No. 649/2012 concerning the export and import of danger chemicals, Annex V together amendedNot listed.Regulation (EC) No. 166/2006 Annex II Pollutant Release and Transfer RegistryNot listed.Regulation (EC) No. 1907/2006, REACH post 59(10) Candidate list as right now published through ECHANot listed.Authorisations:Regulation (EC) No. 1907/2006, reach Annex XIV Substances subject to authorization, as amendedNot listed.Restrictions top top use:Regulation (EC) No. 1907/2006 Annex XVII Substances topic to border on marketing and also useNot regulated.Regulation (EC) No. 1907/2006, reach Annex XVII Substances subject to restriction on marketing and also use asamendedNot listed.Directive 2004/37/EC on the defense of employees from the threats related come exposure come carcinogens and also mutagensat workNot regulated.Directive 92/85/EEC: on the safety and health that pregnant workers and workers who have recently provided birth orare breastfeeding.Not regulated.Other EU regulations:Directive 2012/18/EU on significant accident hazards involving dangerous substancesNot listed.Directive 98/24/EC top top the protection of the health and safety of workers from the risks related to chemical agentsat work.Always applicable.Directive 94/33/EC on the protection of young world at workNot listed.Other regulations: The product is classified and labelled in accordance with EC directives or respective nationwide laws.This safety and security Data Sheet follows the requirements of Regulation (EC) No 1907/2006, together amended.SARA 311/312 HazardsAcute wellness Hazard: Yes.Chronic health and wellness Hazard: No.Fire Hazard: Yes.Reactive Hazard: Yes.Clean Water Act: CWA-Toxic Pollutants: ListedClean wait Act: not applicable.OSHA: no applicable.CERCLA: This material consists of one or much more substances regulated together a hazardous substance under the ComprehensiveEnvironmental response Compensation and Liability action (CERCLA) (40 CFR 302).Hazardous building materials RQs: 1000 lbMassachusetts best to recognize Components: CAS No. 7440-66-6Pennsylvania best to recognize Components: CAS No. 7440-66-6New Jersey right to understand Components: CAS No. 7440-66-6California Prop. 65 Components: This product does not contain any type of chemicals known to the State that California tocause cancer, bear defects, or any other reproductive harm.U.S. Department of TransportationReportable quantity (RQ): No.DOT maritime Pollutant: No.DOT Severe maritime Pollutant: No.U.S. Room of countryside Security: This product does no contain any type of DHS chemicals.Other international RegulationsCanada: This product has actually been divide in accordance with danger criteria the the Controlled commodities Regulations(CPR).WHMIS hazard Class: B6 Reactive flammable material.National regulations: Follow nationwide regulation for work-related with chemistry agents.Chemical safety and security assessment: No Chemical security Assessment has been brought out.SECTION 16. Other INFORMATION