Dichloromethane or methylene chloride, v the chemistry formula CH2Cl2, is a colorless, volatile liquid with a boiling point of 39.6 °C. And a melting point of -96.7 °C. That is widely used as a solvent in chemistry laboratories.

You are watching: What is the lewis structure for ch2cl2

It is polar because of the visibility of 2 chloro groups yet is not miscible through water; however, it does display miscibility with miscellaneous organic solvents such together chloroform, carbon tetrachloride, hexane, benzene, ethyl acetate, and alcohols.

The ready of CH2Cl2 involves a high-temperature treatment of methane or chloromethane through chlorine gas.

CH2Cl2 is considered toxic; that overexposure via inhalation leader to dizziness, nausea, numbness, and also weakness. The is additionally metabolized in the human body to form carbon monoxide and also can cause poisoning.

CH2Cl2 Lewis Structure

The Lewis theory of chemistry bonding—although fairly primitive and the most limited theory on digital structure—does help one come determine just how valence electrons room arranged around the constituent atom in a molecule.

The function of this concept is to assist visualize the chemical bonding of atoms in molecules.

Electrons are stood for as dots, and each pair the bonding electrons in between two atoms is shown as a line. The structures attracted using this theory space termed Lewis (dot) structures.

Please note that several atoms monitor the octet rule, i.e., they tend to attain eight electron in your valence shell through chemistry bonding; this is reflected in the Lewis structure of the molecule.

Hydrogen, however, does have tendency towards a duplet, no octet, since it has actually only one electron in that is K shell, and thus needs only one much more to accomplish the maximum volume of the K shell.

Let us take a look in ~ the chemistry bonding stood for by Lewis structure in CH2Cl2.


Step 1. We shall begin by calculating the number of valence electrons in each atom the CH2Cl2 in stimulate to see how brief an atom is from an octet (or duplet in the case of hydrogen).

i. The atomic variety of carbon is 6; therefore, it own 6 electron in that is neutral form. There space 2 electron in that K shell and also 4 electrons in the together shell. Thus, the variety of valence electrons is 4. To attain the octet, carbon needs 4 more electrons.

ii. Similarly, the atomic variety of hydrogen is 1; thus, each H has actually 1 electron and needs 1 an ext to attain the duplet.

iii. The atomic number of chlorine is 17. K shell has actually 2 electrons, l shell has 8, and M shell has actually 7 electrons. The number of valence electrons is thus 7, and also hence Cl requirements 1 an ext to achieve the octet.

Step 2. Next, us shall number out the main atom to which the remainder of the atoms shall be bonded. The main atom is the one that has actually the greatest bonding capacity; it is the atom that is the shortest the the octet. In CH2Cl2, carbon satisfies this condition (4 electrons short of the octet versus 1 because that chlorine).

Step 3. Now, we shall build a skeleton that the molecule through carbon as the main atom. Carbon demands 4 much more electrons for its octet to it is in complete. 2 hydrogen atoms and also two chlorine atom can assist carbon accomplish this feat!

Simultaneously, both hydrogen atoms will achieve their particular duplets, and both chlorine atom will achieve their corresponding octets, and thereby the case will be a win-win because that all 5 atoms.

Carbon will certainly be singly external inspection to H, H, Cl, and Cl, as displayed in the Lewis structure.

The molecule is neutral, i.e., over there is no fee on it. Let united state calculate the formal charges on each of the constituent atoms. The formula for the formal charge is together follows.

Formal charge (FC) = Valence electron – 0.5*bonding electrons – non-bonding electrons

For carbon, FC = 0; because that hydrogen, FC = 0; and also for Cl, FC = 0.

CH2Cl2 Hybridization

A link is formed between two atoms by the virtue that the overlap the orbitals on 2 atoms as these orbitals share electrons.

Let us look in ~ the ground state digital configuration of each atom in CH2Cl2 in terms of the orbitals.

C: 1s22s22px12py12pz0

H: 1s1

Cl: 1s22s22px22py22pz23s23px23py23pz1

Carbon, in the excited state, has one the the 2s electrons promoted to 2p; therefore, the digital configuration i do not care 1s22s22px12py12pz1. 2s, 2px, 2py, and also 2pz orbitals the carbon are currently half-filled.

These 4 orbitals hybridize together to type four identical sp3 orbitals, every one of which have the very same energy. Each of these hybrid orbitals has actually one electron and also can accept one more.

One electron each originates from H, H, Cl, and also Cl atoms: 1s1 of each H and 3pz1 of each Cl. This leads to the formation of four single bonds (also referred to as sigma bonds) with four sp3 hybrid orbitals the carbon.

Another method of determining the hybridization of the central atom is by making use of the adhering to formula.

Hybridization = A + (VE – V – C)/2,


A is the variety of atoms/groups attached come the main atom;

VE is the number of valence electron on the main atom;

V is the valency of the main atom;

C is the charge on the central atom.

Value that H

Herein, A = 4, VE = 4, V = 4, C = 0; therefore, Hyb = 4, equivalent to sp3.

CH2Cl2 molecular Geometry


The geometry the a molecule have the right to be figured out using the hybridization the the main atom. Matching to sp3 hybridization, the geometry is tetrahedral once there space no lone bag of electrons on the central atom.

Valence shell electron pair repulsion (VSEPR) theory helps to recognize the geometry of a molecule on the basis of stoichiometry, the number of bond pairs, and also the variety of lone bag on the central atom.

The basic idea behind this concept is the a molecule adopts such an arrangement of its constituent atoms the the repulsion occurring from the valence covering electrons on every atoms is minimum.

The complying with table lists this information—on the communication of VSEPR theory— for miscellaneous molecular stoichiometries.


According to the over table, the geometry that CH2Cl2 is tetrahedral, matching to the problems stated because that AX4.

The tetrahedral shape of CH2Cl2 is no perfect unlike the of CH4. This is since CH4 has all the similar hydrogen atoms around carbon, whereas CH2Cl2 has actually 2 H and also 2 Cl.

This is reflected in the slight asymmetry in the molecular shape of the latter. This method that the link angles and bond lengths in CH2Cl2 space not identical; however, all bond angle are the same in CH4.

CH2Cl2 Polarity

The CH2Cl2 molecule is polar in nature.

As the form of the molecule is tetrahedral and also Carbon and Chlorine have a distinction in your electronegativity. The asymmetric shape and also electronegativity difference in between atoms is crucial aspect in determining even if it is a molecule is polar or not.

Thus C-Cl link is polar and also the overall charge distribution across the molecule is non-uniform. For in-depth information, you must read the end an article on the polarity that CH2Cl2.

Molecular orbit Diagram because that CH2Cl2

The premise that molecular orbital (MO) theory is the all the ingredient atoms add towards the development of molecular orbitals, which are a linear mix of the atomic orbitals. Together per this theory, the electrons in a molecule space not personally assigned to atomic orbitals but to molecular orbitals.

Check the end the MO diagram because that CH2Cl2. The 2s and also 2p orbitals that carbon mix (to different extents) with 1s orbitals the the two hydrogen atoms and also 2pz orbitals that the 2 chlorine atoms.

Note the there are 8 atom orbitals mix to form 8 molecule orbitals. The level of mixing and also thus the contribution of individual atom orbitals to form a details molecular orbital counts on the relative energy alignment that the atom orbitals.

Electron pour it until it is full starts native the least energetic molecular orbital. The filled molecule orbitals are called bonding orbitals; the unfilled ones room anti-bonding orbitals.

When over there is a lone pair an atomic orbital, the atomic orbit does no mix with any kind of other orbital and forms a non-bonding molecular orbital.

See more: All Of A Sudden Vs All The Sudden, All Of A Sudden—How To Use It Correctly



The overview provided in this article helps in establishing a straightforward understanding of the structure of CH2Cl2 v chemical bonding.